Influence of Surface Roughness on the Time-Scale of Three Phase Contact Formation by Bubble Colliding with Hydrophobic Solid

Dynamics of collision and kinetics of the bubble attachment to hydrophobic solid plates (Teflon) of different surface roughness were investigated. The experiments were carried out in such a way that probability of the collision and probability that the detachment will not occur were equal always 100%. Thus, it was possible to determine effect of the surface roughness on the bubble attachment (three phase contact formation, TPC) only. A high-speed camera (1182 Hz) was used to record the velocity variations, bouncing and time of attachment of the bubble colliding with Teflon plates having different surface roughness (5 different plates). Roughness of the plate surfaces was modified in a mechanical way using different abrasive papers. It was found that the roughness had a crucial influence on the time-scale of the TPC formation and attachment of the bubble colliding with the Teflon plates. Despite high hydrophobicity of all plates (contact angles 1100 -115º) it was observed that at the smoothest surfaces (called "Teflon I" and "Teflon II" and having surface roughness below 1 um) there was no attachment during the bubble first collisions. Prior to the attachment four or more "approach?bouncing" cycles of the colliding bubble were observed there and simultaneously the bubble shape varied rapidly within time intervals below 0.85 ms. Time of contact of the colliding bubble with the Teflon plates was very short; 2-3 ms. These results indicate that during that short time of the collision the liquid layer separating the colliding bubble and the solid surface did not reach a critical thickness of its rupture.