Influence of the Surface Chemistry and Structure of Activated Carbon on the Adsorption of Aurocyanide

Synthetic and commercial activated carbons are characterised for several chemical and physical properties. A range of techniques is used to establish correlations between physicochemical parameters and gold- adsorption activities. The most important parameter in the carbon activation process for a product with a high gold-adsorption activity is the activation temperature. High activation temperatures yield products with large micropore volumes which provides sites that are ideal in size for adsorption. The surface area of an activated carbon is not necessarily a good measure of its adsorption activity. Surface oxygen-containing functional groups are identified by Fourier transform infrared spectrophotometry to be comprised mainly of ethers and hydroxyls. These functional groups line the edges of the micropores imparting a polar character to the pore and aid in the solvation of the adsorbate. Oxidants such as nitric acid result in a proliferation of surface carboxyl groups. resulting in a negatively- charged surface that is not conducive to the adsorption of gold.