Interaction between copper mattes and refractories

The objective of this investigation was to investigate interactions between high-grade copper mattes and Rexal 60DB direct bonded basic bricks. The infiltration and attack of Rexal 60DB bricks by copper matte and continuous converter matte was investigated in laboratory tests at temperatures up to 1300 °C. The brick dissolution and infiltration tests did not show any significant difference between the 70% Cu and the 81% Cu mattes. More metallic copper was visible in the pores in the case of 81% Cu matte. An important mechanism for direct-bonded magnesia-chrome brick destruction is that oxysulphides start to infiltrate the brick, followed by slow oxidation of the matte producing metallic copper and cuprous oxide, which then react with MgO and Cr2O3, primarily attacking the direct bonds of the brick.