Kinetic Model of the Bacterial Leaching of Chalcopyrite Concentrates

Existing models proposed for the bacterial leaching of metal sulfides generally fail to predict solubilization rates at times greater than a few tens of hours. The reasons for this may be that these models are empirically based and use first order bacterial and chemical oxidation rates. This type of model is satisfactory for short time predictions (on the order of 20 hours) when the bacterially catalyzed dissolution is relatively minor. However, when bacterial action becomes more pronounced, these models consistently predict higher dissolution rates than those commonly observed in laboratory experiments. The present model uses several fundamental chemically and biologically based assumptions to predict the dissolution rate of a chalcopyrite concentrate for extended leach times up to the precipitation of jarosite. The main assumptions made are that Monod growth kinetics prevail, T. ferrooxidans adsorb onto the surface of the mineral (not necessarily mineral specific), and that during periods of high growth oxygen transport may become rate limiting. The model also relies on the energy efficiency of the bacteria in fixing carbon (growth yield) and correlates this value with available surface area of the mineral particles and the bacterial growth rate.