Laser-induced Luminescence and Breakdown Spectroscopy Evaluation of Phosphates with High Dolomite Content

Laser-induced luminescence and breakdown spectroscopy methods appear to be a good tool for real-time evaluation of dolomite content on moving belt. The distinctive feature for time- resolved luminescence is Dy3+ emission in apatite, which is excited by 251 nm laser light and detected with delay time of 5 ms and gate width of 1 ms. The distinctive features for breakdown spectroscopy are 604 nm line of F and P in apatite and 518 nm line of Mg in dolomite. The representative sampling of more than 200 pebbles has been studied by both methods. By luminescence method 100% of dolomite will be identified, while approximately 15-20% of apatite with extremely week Dy3+ luminescence may be mistakenly counted as dolomite. By breakdown spectroscopy the identification is 100% correct both for dolomite and for apatite.