Leaching Of Selenides And Tellurides - Anodic Slimes From Electrolytic Copper Refining

SELENIUM AND tellurium are by-products of electrolytic copper refining. Copper anodes contain 0.01-0.2 % Se and up to 0.04 % Te; during electrolysis these deposit as a slime at the bottom of the cell. Such slimes contain 2-15% Se and 0.5-8 % Te, as selenides and tellurides of gold, silver, and copper. The following compounds have been identified in the slimes: (Ag, Au)Te2, Ag2Se, Ag2Te, CuAgSe, Cu2Se, Cu2Te. Anodic slimes from copper electro¬lytic refining are a grayish black powder, minus 200 mesh. When this complex mixture is decomposed in an acid medium, elemental selenium and tellurium can be obtained, while in an alkaline medium, both metals go into solution. Acid leaching The slime is charged in acid digesters of 800-900 lb capacity, heated to 260°C with 78 % H2SO4, for 8-12 hr. During digestion the following reactions take place: