Limestone in the Pulp and Paper Industry

THERE are many varieties of limestone, but for the general purposes of the pulp and paper industry, two classifications are sufficient: (1) High-calcium stone, which should be quite free from impurities and contain not less then 90 per cent calcium carbonate. (2) High-magnesium stone, containing not less than 25 per cent of magnesium carbonate. Before proceeding with detail on the use of limestone and lime in the industry, a few words regarding the pulp products made in Canada are desirable. By far the largest tonnage is made by grinding spruce and balsam logs on rotating sandstones or on artificial abrasive stones of the Norton or Carborundum types. This mechanical or groundwood pulp finds its largest use in the production of newsprint paper, of which it comprises about 80 per cent of the total fibrous substance employed-the remaining 20 per cent being unbleached sulphite pulp. No limestone or lime is directly employed in making groundwood pulp, as contrasted with the chemically prepared pulps, all of which require one or the other form of the base for their processing. Sulphite pulps comprise the next largest tonnage group. They are produced by boiling, under pressure and at elevated temperatures, spruce and balsam wood in chip form in solutions of bisulphites and sulphurous acid. The usual bisulphites employed are those of calcium and magnesium. Sodium, potassium, and ammonium bisulphites give progressively better pulps, but to date, in the absence of efficient recovery methods, cost has precluded their use.