Limitations Of SEM/EDS Techniques For Particle-By-Particle Analysis In Respirable Coal Dust

The applicability of SEM/EDS techniques to particle-by-particle analysis of respirable coal dust is evaluated. It is demonstrated that the correction procedures needed to account for the failure of most EDS systems to detect light elements (especially carbon) become unreliable for particles in the respirable size range (< 10 µm). Other serious limitations arise from x-ray counting errors for coal particles with low but significant mineral content and particle counting errors for liberated mineral matter.