Losses Of Oxime Type Extractants By Chemical Degradation And Entrainment

Two modes of potential loss of oxime extractants in liquid extraction processes for the extraction of copper have been studied. In loss "by chemical degradation, two mechanisms of acid hydrolysis are possible, some reagents degrade primarily in the organic bulk phase, Others at the interface between the organic phase-- phase protects the oxime but salts added to the aqueous acid phase can promote the rate of degradation. The reagents reported on are the LIX series (Henkel Cpn), SME529 (Shell Chem.Co.) and P5100 (Acorga) Loss by organic entrainment in the aqueous phase leaving mixer-settlers has also been studied, parameters investigated including impeller/tank geometry and the phase inlet arrangements. The consequences of extractant loss by the above mechanisms...are commented upon. They include the direct economic cost, the possible environmental problems and the implications for downstream operations such, as electrowinning.