Magnesia from Magnesite by Calcination/Carbonic Acid Leaching: Precipitation from Solution and Final Product Recovery

Tests show how that temperature and rate of sparging to remove carbon dioxide determine the rate of precipitation and the chemical and physical properties of hydrated magnesium carbonates precipitated from clarified magnesium bicarbonate liquors derived from crude magnesia. At temperatures above 55°C the product is largely in the form ofhydromagnesite, Mg5(C03)4(OH)2.4H2O Between I5°C and 55°C the major product is nesquehonite, MgCO3·3H2O, although partial hydromagnesite precipitation can be induced by a high rate of aeration.As a result of the reduced time required to bring about greater than 95 per cent magnesium precipitation, the higher MgO content of the product, the ease of product recovery from the precipitation vessel, and the lower energy requirement for thermal decomposition of the precipitate to magnesia, it is preferable to precipitate hydromagnesite rather than nesquehonite. Moreover, the magnesia produced from hydromagnesite is somewhat more reactive than that formed from nesquehonite.Using precipitate calcination temperatures less than 1000°C, the chemical reactivities of the magnesias formed from both precipitates are greater than those of the crude magnesias derived from Savage River magnesite itself. The magnesias would be suitable for most uses developed for caustic-calcined magnesia. However, for refractory brick manufacture, it would be necessary to briquelle the caustic-calcined magnesia. adjust the CaO and SiO2 contents and sinter at temperatures in excess of 1600°C. This would bring about an increase in the bulk density and induce the appropriate chemical bonding reactions.Dead-burned magnesia produced from Savage River magnesite by the calcination/carbon dioxide route would have very low B2O3 contents, typically less than 0.0001 per cent.