Mineral and Molecular Design of Flotation Reagents

"At present the traditional study of crystal lattices of nmerials in a topic “flota tion mineralogy ” is used up. The present investigation is development of the a sclsical approaches to t he analy sis of ideal crystal lattices and f ormation on the basic obtained results of consultation, having practical chara cter.The strategy of develop ment floatation reagents i s offered, which basic pr inciple – complementary assembling m olecules forming surface co mpounds so thatth e steric charact eristic of the “visitor "" (of a polar gro up of molecule SAS) corresponded to the st er ic requirements of the ""o wner"" (elementary cell of a mineral), or coincided inter molecular cavities). In itsh case process of for mation of surface com pounds ca n be considered(a first approximation) as a realization of a principle of the design er "" LEGO "".The approach, which basic idea consi deration actioonf reactant ions and ions of ele mentary cell as three-di mensional objects is developed. And at suchp paroach the laws of a ster eometry - laws describin g spatial effect s are applicable. Thus it is possible toconsider a miner al surface as a mat r ix - basis for formation of the requirem ents to polar group of a molleec cuollector, and or (it is possible) depressant. As a whole approach represents a generalized principle double com plementation, enveloping both power, and geometric asp ects (concept ""lock "" and “key "" - spatial conform ity. Figure 7 (left). Fragment of a crystal lat tice of ap atite. Oleic acid ions interact on ly with th e calcium cations locate d on a long axi s of an elementary c ell. Magenta colour represe nts the calciu m cations, which are n ot particip atin g in interactio n, as th e degree of screening by ions neighbours exceeds 1.Figure 2. (right)The illustration of space complementary. “Afterbuilding” an elementary cell of apatite (radical PO4) related molecules of the visitor – alkyl phosphate (polar group PO4). Cations of calcium are not shown."