Mineral Distribution Maps: A Tool to Identify Heterogeneous Water-Rock Reactions in a Future Pit Lake, Martha Mine, New Zealand

Water-rock reactions such as pyrite oxidation and calcite dissolution strongly influence the pH of pit lakes that develop in open-cast mines after mine closure. The Martha Mine, located in world-class epithermal Au-Ag deposit at the southern end of the Coromandel Peninsula, New Zealand, is scheduled to close in 2007, after which the pit excavation will be rehabilitated into a recreational lake; the first pit lake in New Zealand. Mineral distribution maps from XRD results of 130 andesite samples identify regions that could produce or consume acidity in the future pit lake. Maps show pyrite, calcite, adularia, albite, illite and chlorite distribution in the wall rocks. These data identify five alteration mineral associations: potassic, propylitic, weathered, oxidised and weakly-altered. Pyrite occurs in potassic, propylitic and weathered associations, whereas calcite is restricted to propylitic association in the northeast wall. Subaerial, epilimnion, and hypolimnion exposure zones describe the physical and chemical weathering processes that are likely to occur in regions of pit wall, and the potential effects on lake water chemistry. The pH of epilimnion water will depend on the relative abundance of pyrite and calcite in the propylitic association in the northeast wall, whereas hypolimnion pH will depend upon the frequency of whole-lake circulation events that distribute dissolved oxygen to deep lake layer. In mines with diverse alteration associations, mineral distribution maps are an essential precursor for accurately estimating water-rock reactions in pit lake environments. Data may be directly incorporated into a quantitative geochemical model of future pit lake water chemistry.