Mitigation and Prevention of Acid Mine Drainage Using Iron Complexing Agents

The use of selected iron complexing agents in preventing or ameliorating acid mine drainage was investigated. The experiments were conducted in weathering columns using refuse samples from a coal cleaning plant. It was observed that the treatment with iron complexing agents significantly altered the rate of oxidation. Some of the reagents tested reduced the rate of oxidation whereas the others even enhanced it. The results showed that a commercial reagent containing oleyl imidazoline was most effective in retarding the oxidation rate. In addition, a simple treatment with this reagent substantially decreased the rate of oxidation of pyrite in a column that was generating acid at a high rate. The effect of this reagent on the surface properties of pyrite was studied by cyclic voltammetry and zeta potential measurements. The decrease in the rate of oxidation resulted from suppression of both anodic and cathodic reactions at the surface of pyrite.