Modeling Mine Water Treatment Processes and Recycle Loops Using GoldPHREEQC

"Design of effective mine water treatment plants depends on the ability to reliably predict treatment outcomes, but systems with multiple chemical and physical treatment processes and recycle loops can be difficult to model. GoldPHREEQC is a modeling framework that integrates mass and flow routing capabilities of GoldSim software and water quality calculations provided by PHREEQC, and is well-suited to modeling parameters of interest in the mining industry, especially metals and sulfate. Physical processes such as membrane separation and greensand filtration are modeled by defining mass rejections for each parameter and flow routing based on vendor projections and bench- or pilot-scale equipment testing. GoldPHREEQC models chemical precipitation processes such as HDS metals removal and gypsum precipitation by (1) performing surface-aging and solubility calculations in PHREEQC and (2) using the GoldSim framework to direct supernatant and precipitate to subsequent process steps. Users can apply this modeling framework to predict effluent water quality, chemical requirements, sludge production, and required equipment capacity to support design, troubleshooting, and cost estimating. INTRODUCTION Design of effective mine water treatment plants depends on the ability to reliably predict treatment outcomes, but systems with multiple chemical and physical treatment processes and recycle loops can be difficult to model. GoldPHREEQC is a modeling framework that integrates mass and flow routing capabilities of GoldSim software (1) and water quality calculations provided by PHREEQC (2), and is well-suited to modeling treatment of parameters of interest in the mining industry, especially metals and sulfate. GoldPHREEQC can also be applied to other water treatment scenarios using inorganic reactions and processes. The GoldPHREEQC model framework moves water and mass between specified model nodes and calculates specified reaction and water quality outcomes. It can be organized to provide flow, load, and concentration information for each location, including effluent and byproduct streams, and outputs can be adapted to include power and chemical costs."