New BESA Insoluble Anode for Electrolysis in Aqueous Solutions

The problem relating to the use of insoluble anodes in acidic and highly aggressive environments has still not been definitely solved, and it is therefore a recurring subject of discussion. The fields of application in which insoluble anodes play a fundamental role are mainly in the electrolytic extraction of metals, in cathodic protection with impressed current, and in the production of oxidized halogenated salts. Based on the foregoing, B.U.S Engitec Servizi Ambientali (BESA) developed an electrode suitable for the use in the above-mentioned system. The basic component of the BESA anode is a bimetallic wire made of a copper rod (core) covered by a thin layer of valve metal, to be chosen between tantalum (Ta) and niobium (Nb). The wires, coated with suitable catalyst (PbO2, Pt or others) are inserted in a plastic frame and fixed to a current feeder by means of a screw, ensuring an optimal contact. Experimental data on the operating conditions, such as kind of electrolyte, current density, electrode potential, corrosion tests and fields of possible application, are described.