New Insights Into The Mechanism Of Shear-Flocculation Of Silica With Fatty Acids (7f155cc8-a145-4d84-9411-06f34bda9205)

The Bureau of Mines has studied the mechanism of shear-flocculation of silica with stearic acid. At pH 6 and 12, shear-flocculation of silica was not observed with up to 10-4M (5 lb/st) stearic acid. However, in the presence of 0.1 M NaCl at pH 6, shear-flocculation was observed at stearic acid concentrations 10-4 M (5 lb/st). Adsorption of stearic acid on silica was studied using stearic acids spin-labelled with a doxyl group. The presence of the spin-labelling group did not greatly affect the shear-flocculation properties of stearic acid. Adsorption of labelled stearic acid on silica was measured as a function of surfactant concentration with electron paramagnetic resonance (EPR) spectroscopy and gas chromatography (GC). The GC results indicate the stearic acid was predominately adsorbed on the surface at concentrations above 10-4 M. From the EPR spectra, the formation of aggregates of stearic acid was apparent at concentrations of approximately 10-414 (5 lb/st). The results are discussed in terms of a possible mechanism for shear-flocculation.