Nickel Recovery from Nickel Refinery Waste Liquor

Considerable quantities of dissolved nickel are lost in the waste liquors from the QNPL nickel treatment plant. Cementation, precipitation and ion exchange techniques were investigated to reduce this loss. Ion exchange was the most successful of the procedures studied and a process for recovering nickel from stripped ammoniacal process liquors was developed in the laboratory and scaled up to plant flow volumes. The system developed uses a carboxylic ion exchange resin operated in a completely ammoniacal cycle. The regenerant is itself regenerable using existing plant, thus the only loss is the stoichiometric value of NH4+ required to displace the exchanged cations from the resin. Existing plant sand/anthracite filter beds have been adapted for use as resin columns containing 3 cubic metres of resin capable of treating effluent at a flow rate of 6000 litres/min.