OFR-45-92 Hydrometallurgical Recovery Of Lead From Blast Furnace Slags - Background And Objectives

The smelting of lead ores has been carried out in southeast Missouri for centuries, and modern smelting practices have generated a variety of waste products. Lead blast furnace slag is one such product, which typically contains 10% zinc, 25% iron and 2% lead. This slag has often been stockpiled on the producing smelter site and accumulations have now reached several million tonnes. It is possible that in the near future these slags will be classified by the federal Environmental Protection Agency as hazardous, and therefore there is considerable interest in possible treatment processes to render the slags non-hazardous by removing the offending metallic elements. To ensure that the overall slag processing costs are kept to a minimum, it is imperative that lead and zinc be recovered in a form suitable for sale or further processing. There are two generic routes for processing blast furnace slags and they involve hydro-metallurgical or pyrometallurgical techniques. With hydrometallurgy, the slags would be leached directly and the metal values recovered from purified leach solution(s) by electrowinning. One problem with processes of this type is that the zinc and lead grades of the slags are low and the iron content is high, and thus the economics of metal production are often not favorable. For pyrometallurgical processing (1), it has been shown that the slags can be fumed to produce an oxide dust containing all the lead and zinc, and representing only a fraction of the weight of the initial slag. The oxide dust may then be processed hydrometallurgical to recover zinc and lead.