Olivine Reactions During Pelletising of Magnetite Ore at High Temperature Under Oxidising Conditions

Magnesium-rich olivine is used as an additive in LKABÆs iron ore pellets in order to improve the high-temperature properties of the finished products. Olivine is only added to the pellets that are manufactured for ironmaking in the blast furnace process. The olivine comes from Minelco/LKABÆs mine at Seqi in Greenland. This dunite complex of Archean age contains about 95 - 98 per cent olivine. The grain size is typically 1 - 3 mm but much larger euhedral olivine crystals are common in the porphyritic type. The serpentinisation is absent or weak. The most common minor minerals are chromite, chlorite, talc, phlogopite, amphibole and pyroxene. The crushed olivine is transported to LKABÆs pelletising plants in Northern Sweden. After grinding, small amounts of olivine are mixed with the magnetite concentrate. The concentrate is rolled into green balls, about 10 - 14 mm in diameter. The moist green balls are transferred into the pelletising machine where the maximum temperature is about 1250¦C. The residence time in the pelletising machine is about one hour. Olivine is used in order to get pellets with better high-temperature properties. This paper deals with the olivine alteration during the pelletising process and the behaviour of magnesium following the decomposition of magnetite. The reactions are quite complex in the pellets because the physico-chemical conditions vary considerably in the process from one process step to another, and in the pellet bed from the top to the bottom. Some olivine particles in the finished product show very slight alteration, some particles are completely decomposed. The formation of the iron-rich coronas around the olivine particles is the most typical alteration. In the finished pellets the magnesium is mainly distributed between the following phases: unaltered olivine, coronas, Mg/Fe-ferrite and silicate slag.