On Improving Desliming: The Use Of Rheology and Surface Chemistry Interactions

Slimes, especially clays, are detrimental to several processes in the Mining Industry. The efficiency of classification, clarification, gravity separation, and flotation decreases significantly in the presence of slimes and clays. This problem is particularly critical in the Phosphate and Sulfide Industries. To reduce the effect of slimes in mineral processing, several desliming techniques and chemical additives are used, such as sodium silicate, sodium carbonate, sulfuric acid, tripolyphosphate, hexameta phosphate, etc. Lately, the Mining Chemical industry has shift to more “Specifically Developed” reagents that offer the most efficient and cost effective performance, mainly using organic polymers. For this purpose, the Mining Chemical Industry needs to understand the crystal chemistry of minerals, the chemistry of the aqueous media, the interactions in solids-aqueous-gas interfaces, the rheology of the system, and the plant operation conditions and parameters. This paper describes the use of surface chemistry fundamentals on the design of an organic polymer capable of modifying the rheology of clayish slurries of a phosphate ore. The change in the rheological characteristics of the clayish phosphate slurries allow fine ore particles to settle faster by reducing the slurry viscosity. Thus, abetter separation of the ore from the slimes is possible using gravitational or centrifugal forces. As examples of the application of this reagent, industrial and pilot plant tests on desliming using tanks and hydrocyclones are presented. These tests showed the reduction of 32%-36% in ore losses for different phosphate ores during desliming operations, and the increase of cyclones desliming efficiency to 80%. Tests were also carried out to improve the rejection of unwanted iron bearing slimes in phosphate feed. These tests demonstrated that it is possible to reduce by 0.25%-1.23% Fe2O3content in the flotation feed product. As a result, significant economical benefits are observed with the use of this new technology without any adverse effect on down stream operations, such as clay settling or phosphate flotation.