On-Stream Analysis (OSA) of Industrial Slurries for Process Control and Optimization Using Laser-Induced Breakdown Spectroscopy (LIBS)

"COREM has developed, specifically for the mineral industry, a mobile laboratory using the Laser-Induced Breakdown Spectroscopy (LIBS) technique. It has been used to perform onstream analysis (OSA) of the chemical composition of slurries in both gold-ore and iron-ore processing plants. Industrial tests have been carried out respectively at La Mine Doyon (Cambior), a gold-ore processing plant near Rouyn-Noranda, Quebec, and at QCM's iron-ore pelletizing plant in Port-Cartier, Quebec. The aim was to demonstrate that the LIBS technique is capable of providing information that meets the needs for process control. C, Si, Ca, Mg, Mn and Al were the elements targeted on iron ore while Cu, Fe, Ag and Au were targeted for gold ore. The results obtained meet or exceed the requirements for process control and consequently clearly show that the LIBS technique is suitable for industrial applications.The feasibility of OSA, through in-plant validations using COREM’s LIBS mobile laboratory, has been demonstrated in four essential aspects: slurry sampling, LIBS chemical measurement, robustness for continuous operation, and functionality for industrial operators.INTRODUCTIONThere is a general need for optimization in the mineral industry. Process control is a favoured means to achieve this goal (McKee 1991). Real-time knowledge of process status is the key to effective control (Da Silva 1994). Only a few techniques, such as XRF, NMR and digital imaging, are currently amenable to chemically monitor industrial processes (Braden 2002). LIBS is an emerging technique with appealing characteristics for on-line and real-time measurement of bulk material (Lorenzen 1992, Palanco 2000). While our ultimate goal is to provide our industrial partners with performing monitoring tools, a shorter-viewed objective is to demonstrate the feasibility of developing a LIBS system for OSA. The LIBS technique has shown interesting capabilities for measuring solids, liquids, dusts and gases. Our work has focused on mineral slurries (Barrette 1999 and 2001, Turmel 1999). Special equipment is needed to perform in-plant validations. A mobile laboratory based on the LIBS technology has been assembled for this task."