Papers - Flotation - Effect of Xanthates, Copper Sulfate and Cyanides on the Flotation of Sphalerite (With Discussion)

Of the various reagents employed in the flotation of zinc-bearing ores none have attained the wide popularity that is enjoyed at present by xanthates, copper sulfate and cyanides. This situation suggests the existence of an unusual dependence in the reactions of these chemicals and of sphalerite. A study of the flotative characteristics of sphalerite when using xanthates as collectors, as related to the chemical properties of copper salts and cyanides, has therefore been conducted at the University of Utah by the writer and his associates1 during the period of 1926 to 1929. In perusing the technical literature concerning the flotation of zinc ores and of zinc-bearing lead and copper ores, a striking and general lack of agreement as to the floatability of sphalerite was observed. The underlying cause for the erratic behavior of sphalerite has not been definitely ascertained but the presence in various proportions of iron sulfide in solid solution in the sphalerite has frequently been implicitly regarded as a major factor in this respect. Although the effect of iron sulfide in solid solution in sphalerite has not been investigated in relation to the behavior of sphalerite in flotation, it is likely that it is not as important a factor as was thought at one time. The variable float-ability of sphalerite has led to the use of fairly large amounts of cyanide to prevent its flotation in the case of certain ores, whereas mere fractions of that amount of cyanide, or even none at all, have been sufficient to achieve the same result for other ores2 Similarly, the amount of copper sulfate used to promote the flotation of sphalerite has been found to vary widely. Effect of Copper Salts in Distilled Water on Sphalerite In the work at the University of Utah, over a year was spent in futile attempts at duplicating experiments until it was discovered that the