Papers - Miscellaneous - Equilibrium Relations in Aluminum-chromium Alloys of High Purity

This is the thirteenth paper of a series from the laboratories of the Aluminurrl Company of America presenting the results of investigations of equilibrium relations in aluminum-base alloys prepared from electro-lytically refined aluminum. The ninth paper, on The Constitution of High-purity Aluminum-titanium Alloys,' presented a type of system that had not previously been encountered in aluminum alloys. Subsequent work has shown that there are several similar binary aluminum diagrams including that of aluminum and chromium. The present investigation was limited to the cxtreme alnminum end of the aluminum-chromium system. The first systematic investigation of the aluminum-chromium equilibrium diagram was carried out by Hindrichs.? The resulting equilibrium diagram with some imaginary additions suggested by Guillet3 is shown in Fig. 1. Recently Goto and D6gane4 investigated the constitution of aluminum alloys containing up to 32 per cent chromium, and presented the diagram that is reproduced in Fig. 2. Wide discrepancies in the two diagrams are evident. The following intermetallic compounds have been reported in the literature: A1Crl5,6 AlloCrlzSi,5 AlCr4,6 AlCr3,7 AlaCr.8 Preparation of Alloys and Chemical Analyses With the exception of sample Y4206, which will be described under Determination of Hyperperitectic Liquidus, the alloys were prepared from electrolytically refined alurninum% Of which the analysis is given in