Phase relations and thermodynamics in the copper-lead-sulphur system

Phase relations within the condensed Cu-Cu2S-PbS-Pb region of the Cu-Pb-S ternary were investigated. The boundaries of the ternary liquid-miscibility gap were redrawn, and the directions of the tie-lines were established by the quenching of samples equilibrated in evacuated and sealed silica capsules at 1473 K. The activities of lead in sulphur-saturated Cu-Pb alloys along the boundary of the miscibility gap were measured by the dew-point technique at 1473 K. From the tie-line distributions, measured lead activities, known activities of the Cu2S-PbS join, and the ternary Gibbs-Duhem integration, consistent sets of activities for lead and copper and partial pressures of sulphur were obtained along the ternary miscibility gap at 1473 K.