Phase Relationships - Phase Equilibria in Hydrocarbon-Water Systems-II. The Solubility of Ethane in Water at Pressures to 10,000 PSI

A preliminary investigation was made to determine the time required to attain equilibrium within the equilibrium cell for this system. Experimental and smoothed data are presented for the solubility of ethane in water for temperatures of 100°, 160°, 220°, 280" and 340 °F at pressures to 10.000 psia. The minimum solubility phenomenon disappears at 10,000 psia within this temperature range. INTRODUCTION .is a continuation of the investigation of the behavior of hydrocarbon-water systems, the experimental data on the solubility of ethane in water have been extended to 10,000 psia. The experimental apparatus, technique, materials, and analytical methods are essentially the same as previously reported.' TIME-CONCENTRATION STUDY Prior to the initial determinations of solubility in the ethane-water system. it was desired to establish the time