Precipitation By Metals - Theory

Precipitation of a metal from an aqueous solution of its salts by another metal is known as cementation, because the precipitated metal is usually cemented on the added metal. This phenomena was once described by the alchemists as "transmutation," when they dipped a piece of iron in a solution of copper sulfate and the iron was coated with a layer of metallic copper. The process can be predicted in terms of electrode potentials. The metal with the more positive (oxidation) potential, as given in Table 13-1 of the electromotive series, will pass into solution and displace a metal with a less positive potential.