Prediction of the volatile mater in coal from ultimate and proximate analyses

Slow pyrolysis experiments were caried out on samples of coal from north em Natal having a volatile mater content ranging between 10 and 25 per cent by mass and a constant particle-size distribution. The tests were conducted at atmospheric pressure in a helium atmosphere, and ata heating rate of 10 KImin and a final temperature of 1220 K. The pyrolysis products were taken as coke and volatile mater (tar and eight other species), and tMir respective yields were measured. The experimental results were used in the modification of an existing mathematical model and in the derivation of new corelations for some of the parameters of the model, so that the volatile products of a coal can be predicted from ultimate and proximate analyses of the coal. The pyrolysis tests showed good agreement between the model predictions and the experimental results.