Process Mineralogy Of Scandium And Europium-Containing Iron-Making Slag

During slow-cooling crystallization of iron-making blast furnace slags, most rare earth elements recrystallize in an artificial "mineral" identified as calcium cerite. Scandium (Sc) and europium (Eu), however, concentrate in a sheetlike "mineral." In this investigation, the mineralogy of this sheetlike "mineral" was studied. It was identified as being in the mica group and was called a rare earth-bearing barium fluorophlogopite. One of the objectives of this study was the recovery of this "mineral." The study indicated that it can be effectively recovered from the slag by flotation using dodecylammonium acetate or a combination of dodecyl-ammonium acetate and sodium oleate as collectors.