Purification of solid from secondary aluminum smelting dross

Secondary aluminum dross, which has been exposed for several years to atmospheric conditions, was characterized using chemical analysis, X-ray diffraction, optical and scanning electronic microscopy, and energy-dispersive spectroscopy. Based on the characterization, a method to purify the solids is presented. This method starts with the washing of the dross in boiling water to eliminate the soluble compounds like Na and K, followed by the physical separation of the metallic aluminum by milling and screening. Finally, an acid lixiviation process is applied using three different acid solutions, HCl, HNO3, and H2SO4. The best results were obtained using HCl. The main insoluble components of the dross after lixiviation were Al, SiO2, and Al2O3. MgAl2O4, AlN, Si, and Na2Al22O3·2H20 species were also found. Based on the alumina content, the solid product could be suitable as a raw material in the manufacture of castable refractories or metal matrix composites.