Quantification of Microsegregation of Rapidly Solidifed Al-Ni Alloys

Powders of Al-50wt%Ni, Al-40wt%Ni and Al-36wt%Ni were produced using the Impulse Atomization technique, a rapid solidification technique. The molten droplets were cooled in-flight by the stagnant helium or nitrogen in the atomizing chamber. The resulting powders were sieved into different size ranges. X-Ray diffraction and neutron diffraction were used in order to quantify the phase fractions in the samples. The computer software GSAS was used to calculate the weight fraction of the existing phases, namely Al3Ni2, Al3Ni and Al, by profile refinement method. The effect of processing parameters, alloy composition and particle size will be discussed in this paper. In brief, no AlNi was found in any of the samples analyzed. Higher cooling rates resulted in the reduction of the ratio of Al3Ni/Al3Ni2. Also, at high cooling rates, Scheil closely predicted the ratio of Al3Ni/Al3Ni2. Some metastable phases were found in Al- 36wt%Ni.