Raman Spectroscopic Analysis Of Diesel/Aerosol Mixtures

Airborne respirable Diesel Particulate (DP) presents an additional health hazard in that it has been shown to be mutagenic. This problem is of increasing concern as more coal mines introduce diesel vehicles. If the DP present in coal mine air is to be controlled it must first be measured. This paper describes development of the laser Raman spectroscopic measurement of the amount of DP in DP/coal mixtures collected on filters in the laboratory and in coal mines. The Raman technique provides a chemical measure of the carbonaceous material in each component, and is not dependent upon particle size. When this work was begun there were no known analytical methods for this measurement. Side-by-side in-mine comparisons of the results obtained from Raman, neutron activation analysis, and size selective analyses (MOUDI and personal samplers) are presented. The neutron activation and size selective analyses were obtained by the USBM Twin Cities Research Center and University of Minnesota. Good agreement has been found among these three methods.