Recent Developments in the Solvent Extraction of Metals

Until very recently the application of solvent extraction to. the recovery of metals has been considered only for ithose operations where no other process was available. In general, .these operations, have involved metals such as 'f uranium or the rare earths, where the value of metal recovered has been very high. As a result, the tendency has been to consider solvent extraction as a very specialised, high cost technique with minimal application in the base metal industry. Since the mid-1960's this attitude has had to be changed drastically with the development of solvents specifically designed for the selective extraction of individual metals such.ascopper. The result is that solvent extraction must now be regarded as a proven hydrometallurgical technique for the recovery of base metals, and in particular copper. The first significant event in the application of solvent extraction to base metals was the production by General M. Inc. of a compound, designated LIX-63 (R)(1), which was a specific extractant for copper from ammoniacal sns. This did not find a wide application, however, because copper solutions with a pH in the applicable range we more readily treated by conventional techniques.