Recovery and Removal of Uranium by Using Biosubstances

Some attempts were made to recover uranium from aqueous systems by using various biosubstances including microbial biomass. Of hundreds species of microorganisms tested, extremely high uranium absorbing ability was found in Pseudomonas stutzeri, Neurospora sitophila, Streptomyces albus and Streptomyces viridochromogenes. In parallel to this research, various kinds of biomass and commercially available crude drugs were screened to measure their abilities to adsorb uranium. Of these biosubstances tested, high uranium adsorbing ability was observed in chestnut skin, Comi fructus, Geranii herba and Chaenomelis fructus. From these results it may be considered that the uranium adsorbing ability of these biosubstances is due to the following; the uranyl ion is co-ordinated by the polyphenolic compounds such as tannin existing in the biosubstances. Along with these fundamental researches, we have developed a new adsorbent, the immobilised persimmon tannin (kakishibu tannin), for uranium and thorium. This adsorbent can accumulate 1.71 g of uranium per gram of the adsorbent (14 mEq/g), and the uranium adsorbing capacity of this adsorbent exceeds by several times that of commercially available chelating resins (2 - 3 mEq/g). We attempted to recover uranium from uranium refining waste water by using the immobilised persimmon tannin. As a result, the immobilised persimmon tannin can recover trace amounts of uranium from uranium refining waste water containing 10 - 15 ppb uranium with high efficiency. Almost all of the uranium adsorbed onto the adsorbent can be desorbed by washing with 0.05 - 0.1 M HCl or H2SO4. Thus, the immobilised persimmon tannin can be used repeatedly in the adsorption-desorption Cycle.