Recovery of Berryllia from Beryl

Finely ground beryl was decomposed by mixing with ground limestone and soda ash andheating at 900¦C for,4-6, hours.The sintered material was then crushed and leached by boiling under reflux with 5N sulphuric acid for up to 4 hours. The liquor containing Be, ; Al, . Fe and, other elements as sulphates, was separated from the residue which consisted mainly of silica and gypsum, either' by filtration or by decantation washing.The clarified leach liquor.was first treated to remove Fed}: , by contacting with a primary amine-kerosene solution in2 counter-current stages. The iron free liquor wa,s then passed to a 4-stage counter-current extraction unit where it was con-tacted with 0.5M di-(2 ethyl hexyl), phosphoric acid (EHPA) in kerosene. The'operating conditions were such that at least 99 p'br cent of the Be and only 7' per' cent of the Al- was, extracted The ,B6`= and. Al were ;stripped from the organic phase by sod-ium hydroxide solution of suitable concentration to form soluble "beryllate" and "aluminate" respectively. Most of the Be was subsequently precipTitated a's Bo(OH)2 by-hoating the alkaline solution to 90C, the Al remaining in solution. After filtra-tion and washing, the Bo(OH)2 could be ignited directly to BeO at about 1000 C or used as a feed to further purification stages aimed at producing "nuclear grade" BeO.A small coaAter-current extraction unit was operated con-tinuously using liquor derived from the sintering and leaching stages. Data obtained in batch laboratory tests were confirmed. A product obtained by ignition of the washed "beryllate" precip-itate contained more than'99 per cent BeO.