Refining Bismuth by Distillation and Chlorination

"AbstractThe experiments described show that crude bismuth metal containing up to 5 per •cent lead, 0.14 per cent silver, 0.015 per cent copper, 0.02 per cent iron, .and small amounts of antimony, nickel, and tin may be refined to a bismuth content of 99.98 per cent by distillation followed by chlorination. It also is shown that bismuth trichloride of high ,purity may be produced by passing chlorine over hot •crude bismuth metal and allowing the resulting vapours to •condense in a cooler .part of the system.IntroductionBISMUTH is used in the production of alloys and pharmaceuticals. During 1952, the New York price for the refined metal was $2.25 per pound in ton lots.Some months-ago a Canadian producer requested the Mines Branch to investigate methods of refining the bismuth which they had been producing. Their crude product had been selling for $1.50 to $1.70 per pound and it was desired to increase its purity to at least 99.98 per cent so that it could be sold for $2.25 per pound."