Removal of Nickel from Lead by Stirring with Elemental Sulfur

The removal of nickel from lead by sulfur drossing was investigated using a technique which models industrial batch decoppering practice. Successful denickeling to 0.005% (Ni)pb was consistently obtained in the absence of silver, well below the experimental equilibrium value of 0.015% but still above levels obtained in industrial practice. Silver appeared to have little effect upon denickeling. The final nickel content was dependent upon the initial nickel content, the total sulfur addition and the stirring time. The presence of nickel was found to give no assistance to successful decoppering. Simul- taneous removal of nickel and copper was observed at silver contents in excess of 0.02%. Extended stirring resulted in a further lowering of the nickel content but reversion of copper to the bullion was observed. Experimental work has shown that nickel can be removed by a standard decoppering operation; a procedure which is used in secondary lead re- fining. Alternatively nickel can be removed during initial decoppering in primary lead re- fining operations.