RI 2485 The Reduction of Iron Oxides by Fuel Gases

"The factors that determine the efficiency of reduction of iron oxides by gaseous reducing agents may be considered in two classes; those which effect the equilibrium between the reacting substances end their products, and those which affect the rete of reaction. Both sets are of prectical importance, the former as influencing the maximum possible efficiency and the latter as determining what fraction of the maximum yield may be readily or profitably obtained. In addition, the thermal changes attending the reduction greatly affect the chance of successful industrial application of any such process, and knowledge of them is necessary for the intelligent design of apparatus and control of the reaction. Some aspects of each of these three divisions of the problem are discussed below.I. The Maximum Reducing Power of Fuel Gases on the Oxides of IronsThe gases that heve been considered specifically in this work are coal gas, water gas and producer gas, typical analyses” of which are given in Table 1 Of the various hydrocarbons represented in Table 1, (several being grouped or averaged as C2R4), methane is the only gas assumed to be capable of existence at appreciable pressures under the conditions of interest here. The equilibria in the several systems which may ensue when one of the above gases is allowed to react with the iron oxides, may therefore be represented in the most general case by equations of the type of the following arbitrarily chosen ones:"