RI 3415 Progress Reports - Metallurgical Division - 26. Fixation Of Sulphur From Smelter Smoke

"Previous investigation 4/ has demonstrated that some of the aliphatic amines are suitable absorbents for 302, This paper reports the results of physical studies of a number of such amines with the object of determining which is most favorable as an absorbent.Monoethanol amine, diethylene triamine, and triethylene tetramine appear to be the most promising of all the amines studied, and most of this report has been devoted to studies of the physical properties of their aqueous solutions, which contain varying amounts of SO2.PURITY OF MATERIALSAll of the amines used were of commercial grade, because the primary object of this research was the investigation of a proposed works process rather than the accumulation of scientific data.The aminoethyl derivitives of ethylene diamine, namely, diethylene triamine, triethylene tetramine, and tetraethylene pentamine, only recently have been produced commercially. The chemistry of aliphatic amines is complex, and these newer derivitives have not been investigated, completely. Chemically pure material is not on the market, and since definite physical standards have not been published, one could not be assured of a pure product even if the commercial material was refined.The compilation of physical constants for the pure amines would involve much time—consuming effort without materially enhancing the value of this paper, as this work was not devoted to the development of fundamental standards."