RI 3651 Manganese Investigation - Metallurgical Division 15 Hydrometallurgical Studies of Manganese Ores - Electrodeposition of Manganese

"IntroductionThe purpose of this investigation was to study the characteristics of the high-acid electrolytic manganese cell with the idea of fitting it into one of the flow sheets being worked out by the Metallurgical Division of the Bureau of Mines for the recovery of manganese from low-grade domestic ores.In construction, the high-acid cell 3/ differs from the low-acid type in that the cathode and anode compartments are separated by a diaphragm of relatively low porosity, such as alundum. This is necessary because in the high-acid cell the two electrolytes are circulated separately. The anolyte is 15 to 30 percent H2SO4. The catholyte consists of a solution of ammonium sulfate and manganese sulfate with a OH of 4 to 3. The only mixing of electrolytes is that resulting from flow through the diaphragms. In the low-acid cell the two electrolytes are not circulated separately and do not differ so widely in hydrogen-ion concentration. Hence, the canvas diaphragm is sufficient.During operation of the cell, manganese is deposited on the cathode, and sulfuric acid is produced in the anode compartments. Various other reactions take place in the cell. There is considerable decomposition of water; hydrogen is evolved at the cathode, and oxygen is liberated at the anode. When lead anodes are used, some hydrated oxides of manganese are formed at the anodes. The quantity of oxides formed is not as great as it is in the low-acid cell, because fewer Mn++ reach the vicinity of the anodes."