RI 4990 A Colorimetric Method For Determining Pine Oil In Water ? Summary

In connection with, a stream-pollution-research project, a colorimetric method was developed for concentrations of 1 to 30 p.p.m, of pine oil in water. The method depends on the stable bluish-green color produced when pine oil is reacted with vanillin-hydrochloric acid reagent at 60° C. for 25 minutes. The colorimetric reaction actually determines alphaterpineol, the principal component in pine oil. Some waters may require a special preparation in which ion-exchange resins are used to remove interference. ACKNOWLEDGEMENTS The author wishes to express his appreciation to A. A. Berk, chief of the Industrial Water Branch, Bureau of Mines, for helpful advice and encouragement during the progress of this work and to B. P. Martinez, chief of the Stream Pollution Research Section, for assistance with the manuscript. Thanks are also due to W. D. Bishop of the Hercules Powder Co., Wilmington, Del., for supplying the principal components of pine oil.