RI 6131 Hydrogen As A Retaining Ion For Rare-Earth Separation By Ion Exchange With EDTA And DCTA

Effective separation of rare-earth mixtures is obtained using hydrogen as a retaining ion at 200° F with ethylenediaminetetraacetic acid (EDTA) eluant. Results obtained in Bureau of Mines bench-scale apparatus and large columns with hydrogen as a retaining ion closely parallel those obtained with copper as a retaining ion. The use of hydrogen as a retaining ion permits EDTA and water, collected before rare-earth breakthrough, to be recovered in a form that allows the material to be recycled without extensive processing. With the exception of yttrium and dysprosium, separation of rare-earth mixtures is improved and throughput is increased by elevated temperatures. Separation with 1,2-diaminocyclohexanetetraacetic acid (DCTA) eluant increases markedly on increasing temperature from ambient to 250° F; however, on the basis of separation efficiency, DCTA does not compare favorably with EDTA.