RI 6154 Experiments In Fused-Salt Electrolysis Of Tungsten

This report presents the results of preliminary studies for the evaluation of some fused-salt electrolytes for refining tungsten metal, and describes the equipment used. Some impurities could be eliminated with electrolytes composed of sodium chloride, sodium iodide, or sodium tetraborate in combination with tungstic oxide or sodium tungstate. Electrolytes composed entirely of chlorides were unusable because of the volatility of tungsten chloride. Refining 96-to 98-percent tungsten to produce a commercial grade was more successful than further refining of 99.9-percent tungsten. No electrolyte tested yielded a product pure in all respects. Electrolyte temperatures of about 900° C were necessary to maintain a good dissolution rate at the anode and acceptable cell operation. Cathode current densities at the beginning of a deposition cycle were limited to approximately 1 ampere per square inch. Higher current densities resulted in a finely divided product that frequently failed to adhere to the cathode. The most conspicuous impurities in the tungsten produced were carbon, iron, and molybdenum; the former two came from the iron cell and the graphite cell liner. Electrolytes com-posed of tungstic oxide or sodium tungstate in sodium iodide, or 2Na, 0.B203, were capable of producing tungsten carbide.