Royal Canadian Mint Silver Electrorefining Bleed Treatment

"In 2005, the Royal Canadian Mint (RCM) commissioned a new silver electrorefining circuit. This circuit was intended to operate with a minimal electrolyte bleed for the control of copper. However, by the time of start-up, the levels of copper-rich silver doré to electrorefining had increased, and despite partial pyro-conversion in a small Top Blown Rotary Converter (TBRC), copper concentration in the silver anode still averaged 7.5%. This necessitated frequent replenishment of the electrolyte with fresh silver nitrate since copper displaced dissolved silver during electrolysis, and therefore requiring a robust copper bleed treatment step in order to maintain cathode silver flake purity at 99.99%. The originally-installed bleed treatment system could not meet the RCM’s needs. A thorough review of known technologies, however, did not indicate one capable of handling the copper load, and resulted, therefore, in the development of a novel copper hydrolysis approach for removal of copper as an insoluble basic nitrate salt, and recovery of the associated nitric acid for re-use in the circuit. Laboratory-scale trials showed reproducible results, and existing equipment was subsequently modified.INTRODUCTIONIn 2005, the introduction of a new silver electrorefining circuit at the Royal Canadian Mint (RCM) initiated changes in the way customer silver, collected from the gold doré circuit, was processed. These circuit changes were discussed in a recent paper (Aprahamian, 2015). A wastewater treatment plant had not been budgeted at the time, and this represented a significant constraint when considering the introduction of a wet processing circuit. After a review of various options, a turnkey silver electrorefining circuit was purchased from a European firm. Initially, enough cells were ordered to produce 2 million oz of fine silver (999), with the option to increase to 5 million oz. The selected equipment was based on a Moebius cell design combined with a silver grain pressure dissolver to produce make-up silver nitrate solution. Additionally, an evaporator/hydrolysis unit included in the package appealed to the Mint Refinery, on the basis that it offered a simple way to bleed dissolved copper in electrolyte without generating effluent."