Selected Physical-Chemical Aspects of Flocculation

"The theory of flocculation usually is in a state of flux, involves many diverse phenomena, and is complex and sometimes contradictory in details. Instead of attempting a general discourse, I shall discuss selected observations made at our Stamford Laboratories, which impinge on theoretical aspects in two somewhat distinct areas of flocculation. Since some of you many not be familiar with flocculation, and :.n order that we all attach the same meaning to the jargon used, I first would like to review briefly a generalized picture of what goes on.Assume we have a suspension of particles in water, with a distribution in the sizes of particles. The surfaces of the particles interact to some extent with the water--· tending to alter the extent of hydration, may generate some ion exchange, all being somewhat variable with time--developing a surface condition which is very complex in details. We refer to this suspension as the ""substrate.""In the usual situation, if the suspension is allowed to stand quietly, the large particles settle out first, with somewhat smaller particles settling more slowly, and then there is a portion of very fine material which takes a long time or doesn't settle out at all. This resistance to settling t~ the very fine particles results from many factors, but all relate back to the size and density of the particles, to their surface properties, and to the other components in the aqueous suspending medium."