Single Mineral Flotation With Linolenic, Linoleic, Oleic, And Stearic Acids

Notwithstanding the fact that unsaturated fatty acids are used in preference to saturated acids for most flotation purposes, information regarding their collecting properties is sketchy. Keck, Eggleston, and Lowry1 reported in 1939 that the collecting power of fatty acids on hematite decreased in the order of oleic, lauric, myristic, palmitic, and caprylic acid. Keck and Jasberg2 described in the same year that "unsaturated oleic acid with 18 carbon atoms was a better collector than saturated stearic acid" for floating magnetite. Gaudin and Cole3 stated in 1953 that the double bonds of oleic and linoleic acid were not oxidized during the flotation of fluorite, whereas the double bonds of linolenic acid were measurably altered even after one single flotation step. In August, 1953, Hukki and Vartiainen4 concluded that the collecting power of palmitic, oleic, linoleic, and linolenic acids on ilmenite, magnetite, pyrite, and rutile increased with an increasing number of double bonds in the acid molecules. This was subsequently proved to be generally true for the flotation of mapganese5, phosphate6, and magnetite7. The above cited literature indicates that, prior to the present paper, only about ten minerals were tested with pure unsaturated fatty acids as collectors.