Solid Electrolytes ù New Techniques in Metal Refining

Specifications on the types and levels of impurities tolerable in metals are becoming increasingly stringent, and are pushing the limits achievable with conventional refining technologies. Particularly difficult is the removal of electrochemically noble elements with low volatilities, such as copper, from more active host metals such as lead, iron and aluminium. Electrochemical refining, utilising the ability of certain solid electrolytes to selectively transport copper or other impurity cations away from the molten host metal into a separate refining phase, may provide an answer to this problem. Numerous studies on solid electrolytes used in concentration sensors have been reported, as well as a limited number on metal refining. Oxygen anion conducting solid electrolytes have been applied to the deoxidation of copper and steel while cation conductors, eg ¯ -alumina and Nasicon materials, have been used to remove lithium and sodium from aluminium. However, solid electrolytes have yet to be applied to the removal of noble elements. The behaviour of solid electrolytes under the extreme conditions of molten metal refining is not well understood. This paper will examine the potential use of solid electrolytes to remove noble metals such as copper from active host metals such as iron. The suitability, and selection criteria of available solid electrolytes for implementation in the metal refining industry in the future will be discussed. In particular, the stability of Cusicon, a copper superionic conductor potentially suitable for use in metal refining, has been assessed and the results of the experiments are presented.