Some Concepts Of The Genesis Of Bioepigenetic Sulphur Deposits

Elemental sulphur occurrences are widely distributed in two geological environments: -1-Basins containing hydrocarbons and zones of Cenozoic vulcanism. However, very few of these constitute deposits large enough to be of commercial importance. Almost all of the elemental sulphur mined in the world comes from bioepigenetic deposits in petroliferous basins. These deposits occur in two general structural styles: diapiric (salt domes) and stratiform. Examples of diapiric deposits occur in the Gulf Coast basins of Texas, Louisiana, and southern Mexico. Examples of stratiform deposits occur in the Fergana and Amudarya depressions of Central Asia, the Mesopotamian Depression in Iraq, the Cis-Carpathian Trough in Poland and Russia, and the Permian Basin in Texas. Economic bioepigenetic sulphur deposits range in size from approximately 1 million tons of sulphur in the smaller salt dome deposits to more than ZOO million tons of sulphur at the Mishraq stratiform deposit in Iraq. Total world production from bioepigenetic deposits amounts to approximately 16 million tons of sulphur per year, one-half of the world's present annual consumption of elemental sulphur. Most of the balance of the annual consumption is recovered from sour gas and petroleum. All bioepigenetic sulphur deposits share remarkably similar origins and characteristics. They are formed by anaerobic bacterial replacement of gypsum or anhydrite in tilted basins where evaporite beds are underlain by petroleum. Figure 1 illustrates a generalized cross-section of a salt dome sulphur deposit. Figures Z, 3, and 4 are cross-sections of three types of stratiform sulphur deposits. In terms of sulphur genesis, the only significant difference between the salt dome and stratiform deposits is that the positioning of the anhydrites above the petroleum in the salt domes is caused by diapiric rather than sedimentary processes. In the salt domes, the residual anhydrites of the cap-rocks are accumulated by solution and removal of halite by artesian ground waters.