Sources of Ore-Forming Materials of the Changpo Carbonate Replacement Tin Deposit in the Dachang Tin Field: Evidence from Oxygen, Carbon and Hydrogen Isotopes

The Dachang tin field with more than one hundred million tonnes of ore at 1% tin and 3% Zn is one of the largest tin fields in the world. It comprises five carbonate replacement tin deposits, of which the Changpo deposit containing about 80 million tonnes of ore at about 1% tin is the largest deposit. The deposit, hosted by middle Devonian limestone, argillaceous limestone and black shale, is genetically related to the Longxianggei granite.The oxygen, hydrogen and carbon isotope data of minerals, rocks and fluids suggest a magmatic fluid which evolved during the crystallization of the Longxianggei granite. Mass balance calculations show that the depletions observed in 180 and 13C values of calcites from the ore bodies to the country rocks were due to continous isotopic exchange reactions between the magmatic fluid and the marine limestones at different W/R ratios and between 300 and 600¦C.