Studies of Compositional and Corrosion Properties of Nanostructured Superhydrophobic Thin Films on Aluminum Substrates

"Superhydrophobic thin films were fabricated on aluminum alloy substrates by chemical etching followed by passivation with organic acid molecules; (ii) electrophoretic deposition (EPD) of functionalized ZnO nanoparticles and (iii) electrodeposition of organic-inorganic composite materials. The physical and compositional analyses of the deposited thin films were characterized by SEM, FTIR, XRD as well as contact angle goniometer. The contact angle and surface roughness of the superhydrophobic surfaces prepared by the chemical etching process were found to be 156° and 2.29 µm, (ii) by the EPD process were found to be 155° and 4.54 µm and (iii) by the electrodeposition process were found to be 159° and 7.11 µm, respectively.The corrosion properties were analyzed with both polarization and electrochemical impedance spectroscopy (EIS) in NaCl aqueous solutions. The results demonstrate that the superhydrophobic thin films on aluminum alloy substrates display better anti-corrosion behavior than the as-received aluminum substrate. The comparison of results pertaining to the compositional and corrosion properties of these thin films on aluminum will be discussed in this work.INTRODUCTIONSuperhydrophobicity is defined as a surface property which provides non-wetting characteristics with a water contact angle larger than 150°. It is observed that the creation of certain micro-nanoroughness structures promotes the entrapment of air in the spaces of the rough surface morphology. In addition, lowering the surface energy helps to reduce the affinity of water drops to the surface, thereby weakening the water-surface interaction. Recently, various fabrication methods for superhydrophobic surfaces have been explored (Sarkar, 2010, Huang, 2010, 2011, 2013, 2015a, 2015b), such as the sol-gel process (Brassard, 2011), plasma treatment (Marchand, 2013), chemical vapor deposition (Zheng, 2009), chemical etching (Saleema, 2011), electrodeposition (Ying, 2011) and electrophoretic deposition (EPD; Huang et al., 2015b)."