Surfactants, Dispersants, Complexants and Flocculants - The Role of Additives in the Processing of Concentrated Particulate Suspensions in the Mining Industry

The use of chemical additives to initiate such processes as particulate separation through flotation or dewatering through flocculation, is common in the mining industry. The dosing of additives is none the less poorly controlled from a process control viewpoint and it is perhaps fortuitous that over-dosing or misuse of chemicals is rarely catastrophic to the production cycle. In many cases, such events would go undetected if it were not for economic considerations. Recently, the advent of orebodies with finer mineral disseminations and the push for greater efficiencies in both production and tailing disposal have resulted in the need for greater control of the dosing and utilisation of chemical additives. The need to grind at higher pulp densities and to finer sizes and to dewater to higher solid contents are but two examples that require a more stringent understanding of the true role of additives in controlling the rheology of suspensions and the influence of additives on the surface chemistry of particles. The inter-relationship between the surface chemistry of particles and the role of additives in controlling suspension rheology is now well understood for systems in which the average particle shape in the mixture is spherical or close to spherical. Luckily, this is the case for a large number of systems in the mining industry and the true role of typical additives in these systems will be explored. Difficulties arise for suspensions containing clays or other platey or needle shaped minerals and in many cases, quite small quantities of platey minerals dominate the rheology of suspensions. The role of additives in controlling the rheology of asymmetric particle systems is more complex but the effect of the additive in changing particle alignment in solution is the key to understanding suspension behaviour. The manipulation of the rheology of asymmetric particle systems will also be explored.